[xcrysden] Fermi surface for FCO
Tone Kokalj
xcrysden@democritos.it
Tue, 21 Jun 2005 00:09:19 +0200 (CEST)
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> Dear Tone,
>
> b/a and c/a in my calculations are far from those for
> HCP structure.
On the contrary, your lattice vectors are very compatible to those for
hexagonal structure. Your primitive lattice vectors (in ANGSTROMS) are:
PRIMVEC
1.3070671900 2.3643091383 0.0000000000
-1.3070671900 2.3643091383 0.0000000000
0.0000000000 0.0000000000 2.9142197535
These are indeed as you indicated:
> Basis vectors BCO (nbrav=9) lattice read from INPUT_PW
>
> a/2 b/2 0
> -a/2 b/2 0
> 0 0 c
But look at above numbers: the angle between a and b vectors is 122.1
deg (57.9 deg), while the other angle is 90 deg. This is quite close
to hexagonal lattice.
The primitive reciprocal vectors are (ANGSTROMS^-1):
RECIP-PRIMVEC
0.3825358052 0.2114782674 0.0000000000
-0.3825358052 0.2114782674 0.0000000000
0.0000000000 0.0000000000 0.3431450216
These are again as you indicated:
> and so basis vectors in the reciprocal space are
> 1 1/(b/a) 0
> -1 1/(b/a) 0
> 0 0 1/(c/a)
>
Indeed, the BZ for this vectors will be very close to that of
hexagonal structure. As you can see from the top side figure (bz.png),
there is a hexagon, but with the angles 118.9 and 122.1 deg!!!
What is strange with your data is your structure: the side view
(struct-side.png) reveals an awkward structure with very close
inter-atomic distance between the two Cu atoms: is this really the
right structure?
On the other hand, if you compare the figures struct-top.png and
bz.png, you will notice they are compatible.
Best regards, Tone
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