Dear Sir,<br>Thanks for reply.<br><br><br><div class="gmail_quote">On Thu, May 26, 2011 at 10:23 PM, Stefano de Gironcoli <span dir="ltr"><<a href="mailto:degironc@sissa.it">degironc@sissa.it</a>></span> wrote:<br><blockquote class="gmail_quote" style="margin: 0pt 0pt 0pt 0.8ex; border-left: 1px solid rgb(204, 204, 204); padding-left: 1ex;">
<div>
with this input the Fe-N distance is some 1.2 A... I'm pretty sure
it cannot be the intended structure<br>
Are you sure the system is not in crystal coordinate ?<br>
stefano</div></blockquote><div>Yes, its true that while looking from xcrysden particularly the bond lengths between the Fe-N and N-N but i am very surprised why both ABINIT and PWSCF code gives such vast Difference in calculated Pressure for the identical geometry which is not cleared yet. Here the bond lenth Fe-N is ~1.24Ang. <br>
Please Suggest More.<br><br><br></div><blockquote class="gmail_quote" style="margin: 0pt 0pt 0pt 0.8ex; border-left: 1px solid rgb(204, 204, 204); padding-left: 1ex;"><div text="#000000" bgcolor="#ffffff"><div><div> </div>
<div></div></div></div></blockquote><blockquote class="gmail_quote" style="margin: 0pt 0pt 0pt 0.8ex; border-left: 1px solid rgb(204, 204, 204); padding-left: 1ex;"><div text="#000000" bgcolor="#ffffff"><div><div> </div></div>
</div></blockquote><blockquote class="gmail_quote" style="margin: 0pt 0pt 0pt 0.8ex; border-left: 1px solid rgb(204, 204, 204); padding-left: 1ex;"><div text="#000000" bgcolor="#ffffff"><div><div class="h5">
<br>
On 05/26/2011 04:13 PM, Sanjeev Gupta wrote:
</div></div><blockquote type="cite"><div><div></div><div class="h5">
<pre>Dear Maxim
Thank for kind reply.
My unit cell is as same in ABINIT as in pwscf in Bohr unit. In addition I
am using the spacegroup 166 (R3(bar)M) space group with conventional unit
cell rather than primitive unit cell the lattice parameter is taken as below
1. for abinit
a=5.359168252 Bohr
b=5.359168252 Bohr
c=20.08294707 Bohr
2. for PWSCF
ibrav=4,
celldm(1) = 5.359168242 Bohr
celldm(3) = 3.7474
Part of my input file is :
PWSCF
&control
calculation = 'scf'
prefix='FeN2',
restart_mode='from_scratch',
outdir='./'
pseudo_dir = '/',
tstress = .true.
tprnfor = .true.
etot_conv_thr = 1.0d-5,
forc_conv_thr = 1.0d-4,
/
&system
ibrav=4,
celldm(1) = 5.359168242,
celldm(3) = 3.7474
nat=9,
ntyp=2,
nosym =.true.,
ecutwfc = 20,
ecutrho=200,
occupations='smearing',
smearing='m-p',
degauss=0.001,
/
&electrons
mixing_mode = "local-TF",
mixing_beta = 0.700000,
conv_thr = 1.0d-10,
/
ATOMIC_SPECIES
Fe 55.845 Fe.pbe-sp-van.UPF
N 14.0067 N.pbe-van_ak.UPF
ATOMIC_POSITIONS
Fe -1.8503717077E-17 -1.8503717077E-17 -1.8503717077E-17
N -1.8503717077E-17 -1.8503717077E-17 4.4000000000E-01
..........................................
N 3.3333333333E-01 6.6666666667E-01 2.2666666667E-01
K_POINTS automatic
6 6 6 0 0 0
Best Regards
Sanjay D. Gupta
Research Fellow
Department of Physics,
Bhavnagar University, Bhavnagar-364 022
Gujarat, Mobile-9879666643
<a href="mailto:email:guptasanjay_56@yahoo.co.in" target="_blank">email:guptasanjay_56@yahoo.co.in</a>
</pre>
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